Search results for " IR spectra"
showing 2 items of 2 documents
Modelling IR Spectra of Sulfonated Polyether Ether Ketone (SPEEK) Membranes for Fuel Cells
2020
Authors acknowledge support from LSC project No 2014/666 ERDF and students ( ) support from project 2DP/2.1.1.1.0/14/APIA/VIAA/009.
Structural and Molecular Characterization of meso-Substituted Zinc Porphyrins: A DFT Supported Study
2011
Structural parameters of a range of over 100 meso-substituted zinc porphyrins were reviewed and compared to show how far the nature of the functional group may affect the interatomic distances and bond angles within the porphyrin core. It was proved that even despite evident deformations of the molecular structure, involving twisting of the porphyrin's central plane, the coupled π-bonding system remains flexible and stable. DFT calculations were applied to a number of selected porphyrins representative for the reviewed compounds to emphasize the relevance of theoretical methods in structural investigations of complex macrocyclic molecular systems. Experimental and DFT-simulated IR spectral …